Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

被引：73

作者：

Hill, MS

Hitchcock, PB

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b305430f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of mononuclear and arene-soluble bis( phosphinimino) methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)(2)] to a mixture of [CH2(Ph2P=NC6H2-Me-3-2,4,6) (2)] and MI2 ( M = Ca, Sr, Ba) in THF.

引用

页码：1758 / 1759

页数：2

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