Pd(OAc)2-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen

被引:222
作者
Nishimura, T [1 ]
Onoue, T [1 ]
Ohe, K [1 ]
Uemura, S [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1016/S0040-4039(98)01235-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel combination of Pd(OAc)(2)/pyridine/MS3A catalyzes the aerobic oxidation of various benzylic alcohols into corresponding aldehydes and ketones in good yield. Primary and secondary aliphatic alcohols also are smoothly oxidized to aldehydes and ketones, respectively, under the same conditions. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:6011 / 6014
页数:4
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