Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis

被引：467

作者：

Dang, Dongbin ^{[1
]}

Wu, Pengyan ^{[1
]}

He, Cheng ^{[1
]}

Xie, Zhong ^{[1
]}

Duan, Chunying ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 41期

关键词：

ALDOL REACTIONS; INDUCTION; SOLIDS;

D O I：

10.1021/ja101208s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homochiral crystallizations of two enantiomeric metal-organic frameworks (MOFs) Ce-MDIP1 and Ce-MDIP2 were achieved by using L- or D-BCIP as chiral inductions, respectively, where the chiralities were characterized by solid state CD spectra. Ce-MDIPs exhibit excellent catalytic activity and high enantioselectivity for the asymmetric cyanosilylation of aromatic aldehydes; the homochiral Cd-TBT MOF having L-PYI as a chiral adduct exhibits stereochemical catalysis toward the Aldol reactions.

引用

页码：14321 / 14323

页数：3

共 17 条

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