Matched/mismatched interaction of a cyclic hexapeptide with ion pairs containing chiral cations and chiral anions

被引：31

作者：

Heinrichs, G

Kubik, S

Lacour, J

Vial, L

机构：

[1] Tech Univ Kaiserslauten, Fachbereich Chem Organ Chem, D-67663 Kaiserslautern, Germany

[2] Univ Geneva, Dept Chim Organ, CH-1211 Geneva, Switzerland

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 11期

关键词：

D O I：

10.1021/jo050215x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The binding of a chiral quaternary ammonium ion to a cyclopeptide containing aromatic amino acid subunits is affected not only by the configuration of the cation but also by the configuration of the chiral counterion. Analysis of the binding equilibria shows that complex formation involves interaction of the whole ion pair with the host indicating that steric requirements of the anion influence complex geometry and stability.

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页码：4498 / 4501

页数：4

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