Heterobimetallic intermediates in alkene insertion reactions into a Pd-acetyl bond

被引：52

作者：

Braunstein, P

Durand, J

Knorr, M

Strohmann, C

机构：

[1] Univ Strasbourg 1, Inst Le Bel, Chim Coordinat Lab, CNRS,UMR 7513, F-67070 Strasbourg, France

[2] Univ Franche Comte, Fac Sci & Tech, Lab Mat Mol & Interfaces, F-25030 Besancon, France

[3] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 02期

关键词：

D O I：

10.1039/b007171o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactivity of diphosphine-bridged heterobimetallic Fe-Pd alkyl complexes was evaluated for the insertion of CO, isonitriles, ethylene, methyl acrylate and norbornadienes and the crystal structures of the precursor alkyl complex, the iminoacyl derivative and the five-membered ring complex resulting from ethylene insertion into the palladium-acyl bond are reported.

引用

页码：211 / 212

页数：2

共 19 条

[1] HETEROBIMETALLIC TEMPLATES FOR CARBON-CARBON BOND FORMATION BY MIGRATORY INSERTION REACTIONS INVOLVING CO, ISONITRILES OR OLEFINS [J].