Optically sensed, molecular shuttles driven by acid-base chemistry

被引:63
作者
Vella, Sarah J. [1 ]
Tiburcio, Jorge [1 ]
Loeb, Stephen J. [1 ]
机构
[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
关键词
1,2-BIS(PYRIDINIUM)ETHANE AXLES; BINDING-SITES; SWITCH; RECOGNITION; 1,2-BIS(4,4'-DIPYRIDINIUM)ETHANE; TEMPLATE; MOTION;
D O I
10.1039/b710708k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A pair of bistable [2] rotaxane, molecular shuttles were prepared that combine 1,2-bis(pyridinium) ethane and benzylanilinium recognition sites; acid-base controlled shuttling of DB24C8 was accompanied by a change in colour and/or fluorescence intensity.
引用
收藏
页码:4752 / 4754
页数:3
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