A versatile copper-induced synthesis of fluorinated oligo(para-phenylenes)

被引：21

作者：

Babudri, F ^{[1
]}

Cardone, A ^{[1
]}

Farinola, GM ^{[1
]}

Naso, F ^{[1
]}

机构：

[1] Univ Bari, Dipartmento Chim, CNR, Ctr Studio Metodol Innovat Sintesi Organ, I-70126 Bari, Italy

来源：

TETRAHEDRON | 1998年 / 54卷 / 48期

关键词：

aryl halides; coupling reactions; oligomers; polyaryls;

D O I：

10.1016/S0040-4020(98)00919-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ullmann-like reductive coupling of 1,4-diiodo-2,3,5,6-tetrafluorobenzene, promoted by copper(I) thiophene-2-carboxylate in N-methylpyrrolidinone at room temperature, followed by treatment with lithium aluminum hydride in THF, allowed us to obtain fluorinated poly(para-phenylene) oligomers containing up to five aromatic rings with hydrogen atoms as terminal groups. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：14609 / 14616

页数：8

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