Graphene oxide/conducting polymer composite hydrogels

被引:267
作者
Bai, Hua [1 ]
Sheng, Kaixuan [1 ]
Zhang, Pengfei [1 ]
Li, Chun [1 ]
Shi, Gaoquan [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
CONDUCTING POLYMERS; ELECTROCONDUCTIVE HYDROGELS; OXIDE SHEETS; POLYANILINE; PROPERTY; FABRICATION; FILMS; WATER;
D O I
10.1039/c1jm13918e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene oxide/conducting polymer (GO/CP) composite hydrogels were prepared by in situ chemical polymerization of corresponding aromatic monomers in aqueous dispersions of GO sheets. GO/polypyrrole (PPy), GO/poly(3,4-ethylenedioxythiophene) (PEDOT) and GO/polyaniline (PANi) hydrogels were obtained by this technique, and the mechanism of gelation was discussed. Among them, GO/PPy composite hydrogels were tested to have low critical hydrogel concentrations (<1%, by weight), high storage moduli (>10 kPa) and electrical conductivity, and strong electrochemical activity. A gas sensor based on a typical GO/PPy hydrogel showed high sensitivity towards ammonia gas.
引用
收藏
页码:18653 / 18658
页数:6
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