Metal-containing ionic liquids and ionic liquid crystals based on imidazolium moiety

被引：281

作者：

Lin, IJB ^{[1
]}

Vasam, CS ^{[1
]}

机构：

[1] Natl Dong Hwa Univ, Dept Chem, Hualien 974, South Korea

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 15期

关键词：

metal-containing ionic liquids; metal-containing ionic liquid crystals; imidazolium; imidazole; carbene;

D O I：

10.1016/j.jorganchem.2005.03.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ionic liquids and ionic liquid crystals of imidazolium salts composed of various transition and main group metals have been reviewed. Ionic metal complexes of imidazoles and N-heterocyclic carbenes possess the similar properties were also included. These types of ILs and ILCs have been realized as potential solvents, catalysts, catalyst precursors and reagents for many organic transformations and provide ecofriendly protocols. They have also been found to play key roles in material science. Many of these IL systems are air- and moisture stable and are considered as alternatives for air- and moisture sensitive chloroaluminate-based ILs. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：3498 / 3512

页数：15

共 148 条

[1] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Munro, HL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011

[2] Ionic liquids based upon metal halide/substituted quaternary ammonium salt mixtures [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, R .

INORGANIC CHEMISTRY, 2004, 43 (11) :3447-3452

[3] Quaternary ammonium zinc- or tin-containing ionic liquids: water insensitive, recyclable catalysts for Diels-Alder reactions [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, RH ;

Tambyrajah, V .

GREEN CHEMISTRY, 2002, 4 (01) :24-26

[4] Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions [J].

Andrus, MB ;

Song, C ;

Zhang, JQ .

ORGANIC LETTERS, 2002, 4 (12) :2079-2082

[5] Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J].

Antonietti, M ;

Kuang, DB ;

Smarsly, B ;

Yong, Z .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :4988-4992

[6] ROOM-TEMPERATURE IONIC LIQUIDS AS SOLVENTS FOR ELECTRONIC ABSORPTION-SPECTROSCOPY OF HALIDE-COMPLEXES [J].

APPLEBY, D ;

HUSSEY, CL ;

SEDDON, KR ;

TURP, JE .

NATURE, 1986, 323 (6089) :614-616

[7]

Aubin S, 2002, ACS SYM SER, V818, P334

[8] An ionic liquid-supported ruthenium carbene complex: A robust and recyclable catalyst for ring-closing olefin metathesis in ionic liquids [J].

Audic, N ;

Clavier, H ;

Mauduit, M ;

Guillemin, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9248-9249

[9] Vanadyl salen complexes covalently anchored to an imidazolium ion as catalysts for the cyanosilylation of aldehydes in ionic liquids [J].

Baleizao, C ;

Gigante, B ;

Garcia, H ;

Corma, A .

TETRAHEDRON LETTERS, 2003, 44 (36) :6813-6816

[10] Carbamoyl-substituted N-heterocyclic carbene complexes of palladium(II):: Application to Sonogashira cross-coupling reactions [J].

Batey, RA ;

Shen, M ;

Lough, AJ .

ORGANIC LETTERS, 2002, 4 (09) :1411-1414

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