Metal-containing ionic liquids and ionic liquid crystals based on imidazolium moiety

被引:281
作者
Lin, IJB [1 ]
Vasam, CS [1 ]
机构
[1] Natl Dong Hwa Univ, Dept Chem, Hualien 974, South Korea
关键词
metal-containing ionic liquids; metal-containing ionic liquid crystals; imidazolium; imidazole; carbene;
D O I
10.1016/j.jorganchem.2005.03.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Ionic liquids and ionic liquid crystals of imidazolium salts composed of various transition and main group metals have been reviewed. Ionic metal complexes of imidazoles and N-heterocyclic carbenes possess the similar properties were also included. These types of ILs and ILCs have been realized as potential solvents, catalysts, catalyst precursors and reagents for many organic transformations and provide ecofriendly protocols. They have also been found to play key roles in material science. Many of these IL systems are air- and moisture stable and are considered as alternatives for air- and moisture sensitive chloroaluminate-based ILs. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:3498 / 3512
页数:15
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