Isostationary functions for multimode and multilevel Jahn-Teller systems

被引:5
作者
Ceulemans, A
Chibotaru, LF
机构
来源
THEORETICA CHIMICA ACTA | 1996年 / 94卷 / 04期
关键词
Jahn-Teller effect; potential energy surface;
D O I
10.1007/BF00186442
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The method of isostationary functions, first introduced for linear Jahn-Teller problems within a single electronic term, is generalized to multimode and multilevel problems. Analytic expressions are obtained for the case of linear vibronic coupling of a general form, including both simply and non-simply reducible groups. It is shown that the static multimode Jahn-Teller problem for non-simply reducible groups can always be reduced to an ideal single-mode problem.
引用
收藏
页码:205 / 212
页数:8
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