Poly[lead(II)-μ-4,4-bipyridine-N:N′-di-μ-bromo]

被引:29
作者
Cui, Y [1 ]
Ren, J [1 ]
Chen, G [1 ]
Yu, WC [1 ]
Qian, YT [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
D O I
10.1107/S0108270100014992
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title complex, [PbBr2(bipy)](n) (bipy is 4,4' -bipyridine, C10H8N2), was obtained by hydrothermal reaction of Pb(O2CCH3), NaBr and bipy. The bipy group acts as a linear bifunctional bridge forming a planar {-[Pb(bipy)]-}(n) belt in the direction of the b axis. The remaining lead coordination sites are occupied by Br ions which link Pb centres in adjacent belts through double bridges to form extended two-dimensional layers.
引用
收藏
页码:E552 / E553
页数:2
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