Synthesis of p-tert-butylcalix[4]arene dinitrile bonded aminopropyl silica and investigating its usability as a stationary phase in HPLC

被引：25

作者：

Gezici, O ^{[1
]}

Tabakci, M ^{[1
]}

Kara, H ^{[1
]}

Yilmaz, M ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, TR-42031 Konya, Turkey

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 2006年 / A43卷 / 02期

关键词：

calixarene; immobilization; aminopropyl silica; HPLC; nucleo bases; nucleosides; aromatic compounds;

D O I：

10.1080/10601320500437060

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The chromatic separation of adenine, adenosine, cytosine, phenol, benzene, and toluene were investigated by using 5,11,17,23-tert-butyl-25,27-bis(cyanomethoxy)-26-(chloroformyl)-28-hydroxy-calix[4]arene bonded aminopropyl silica (CDBAPS) as a stationary phase. The separation ability of the stationary phase was observed to be good for target species. The effect of non-polar calix[n]arene network was observed in chromatographic processes, and it was thought that, thanks to the relatively polar nitrile groups, further selectivity would be obtained in various chromatographic separations.

引用

收藏

页码：221 / 231

页数：11

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