A fourier-transform infrared and laser-Raman spectroscopic investigation of 4,4'-bipyridyl-transition metal(II) tetracyanonickelate clathrates

被引：9

作者：

Akyuz, S

Akyuz, T

Davies, JED

机构：

[1] CEKMECE NUCL RES & TRAINING CTR,HAVALIMANI,ISTANBUL,TURKEY

[2] UNIV LANCASTER,DIV ENVIRONM SCI,LANCASTER LA1 4YQ,ENGLAND

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1996年 / 26卷 / 1-3期

关键词：

tetracyanonickelate compounds; benzene clathrate; aniline clathrate; IR and Raman spectra; 4,4'-bipyridyl complexes;

D O I：

10.1007/BF01029935

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The FT-IR and Raman spectra are reported of M(4, 4'-bipyridyl)Ni(CN)(4) . nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline; n = 0-2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)(4)}(infinity) and 4, 4'-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4, 4'-bipyridyl molecules are found to be centrosymmetric in the structure.

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页码：111 / 117

页数：7

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