Synthesis and structure of the new ternary nitride SrTiN2

被引：30

作者：

Gregory, DH

Barker, MG

Edwards, PP

Siddons, DJ

机构：

[1] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England

[2] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 15期

关键词：

D O I：

10.1021/ic971556z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new ternary nitride, SrTiN2, has been synthesized by the solid-state reaction of Sr2N with TiN and characterized by powder X-ray diffraction. SrTiN2 crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Angstrom, c = 17.6985(4) Angstrom Z = 2) an is isostructural with KCoO2. Titanium is-coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layers and is coordinated to five nitrogen atoms. The title compound is only the third example of a ternary titanium nitride.

引用

收藏

页码：3775 / 3778

页数：4

相关论文

共 37 条

[1] The high temperature preparation and property measurements of CaTaN2: A ternary superconducting nitride [J].

Balbarin, V ;

VanDover, RB ;

Disalvo, FJ .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (12) :1919-1927

[2] SYNTHESIS OF THE NEW TERNARY TRANSITION-METAL NITRIDE FEWN2 VIA AMMONOLYSIS OF A SOLID-STATE OXIDE PRECURSOR [J].

BEM, DS ;

LOYE, HCZ .

JOURNAL OF SOLID STATE CHEMISTRY, 1993, 104 (02) :467-469

[3] SYNTHESIS, CRYSTAL-STRUCTURE, AND PHYSICAL-PROPERTIES OF SR2N [J].

BRESE, NE ;

OKEEFFE, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1990, 87 (01) :134-140

[4]

BRESE NE, 1992, STRUCT BOND, V79, P307

[5] SYNTHESIS, STRUCTURE, ELECTRIC, AND MAGNETIC-PROPERTIES OF CANIN [J].

CHERN, MY ;

DISALVO, FJ .

JOURNAL OF SOLID STATE CHEMISTRY, 1990, 88 (02) :459-464

[6] STRUCTURE OF VACANCY-ORDERED TITANIUM HEMINITRIDE DELTA'-TI2N BY POWDER NEUTRON-DIFFRACTION [J].

CHRISTENSEN, AN ;

ALAMO, A ;

LANDESMAN, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (JUL) :1009-1011

[7] NEUTRON-DIFFRACTION INVESTIGATION ON SINGLE-CRYSTALS OF TITANIUM CARBIDE, TITANIUM NITRIDE, AND ZIRCONIUM NITRIDE [J].

CHRISTENSEN, AN .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1975, 29 (05) :563-564

[8]

Clark H.T., 1949, J MET, V1, P588

[9] CA6GAN5 AND CA6FEN5 - COMPOUNDS CONTAINING [CO3]2--ISOSTERIC ANIONS [GAN3]6- AND [FEN3]6- [J].

CORDIER, G ;

HOHN, P ;

KNIEP, R ;

RABENAU, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 591 (12) :58-66

[10] LIMON2 - THE 1ST METALLIC LAYERED NITRIDE [J].

ELDER, SH ;

DOERRER, LH ;

DISALVO, FJ ;

PARISE, JB ;

GUYOMARD, D ;

TARASCON, JM .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :928-937

← 1 2 3 4 →