Anomalous temperature dependence of vibrational lifetimes in water and ice

被引：246

作者：

Woutersen, S ^{[1
]}

Emmerichs, U ^{[1
]}

Nienhuys, HK ^{[1
]}

Bakker, HJ ^{[1
]}

机构：

[1] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands

来源：

PHYSICAL REVIEW LETTERS | 1998年 / 81卷 / 05期

关键词：

D O I：

10.1103/PhysRevLett.81.1106

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We have used femtosecond two-color midinfrared spectroscopy to determine the temperature dependence of the OH-stretching lifetime in dilute HDO:D2O solution, both in the liquid and solid (ice Ih) state. Like many other properties of water, the vibrational lifetime shows a remarkable temperature dependence: In liquid water the vibrational relaxation of the OH-stretching mode is twice as slow as in ice, and becomes even slower with increasing temperature.

引用

页码：1106 / 1109

页数：4

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