Optical fiber-based on-line UV/Vis spectroscopic monitoring of chemical reaction kinetics under high pressure in a capillary microreactor

被引：58

作者：

Benito-Lopez, F

Verboom, W

Kakuta, M

Gardeniers, JGE

Egberink, RJM

Oosterbroek, ER

van den Berg, A

Reinhoudt, DN

机构：

[1] Univ Twente, Lab Supramol Chem & Technol, SMCT, MESA,Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

[2] Univ Twente, BIOS, Lab Chip Grp, MESA,Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 22期

关键词：

D O I：

10.1039/b500429b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With a miniaturized (3 mu L volume) fiber-optics based system for on-line measurement by UV/Vis spectroscopy, the reaction rate constants ( at different pressures) and the activation volumes ( DV?) were determinined for a nucleophilic aromatic substitution and an aza Diels-Alder reaction in a capillary microreactor.

引用

页码：2857 / 2859

页数：3

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