Hexafluoroisopropanol as a highly versatile solvent

被引：697

作者：

Colomer, Ignacio ^{[1
]}

Chamberlain, Anna E. R. ^{[1
]}

Haughey, Maxwell B. ^{[1
]}

Donohoe, Timothy J. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England

来源：

NATURE REVIEWS CHEMISTRY | 2017年 / 1卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

LIVING RADICAL POLYMERIZATION; PROTON-TRANSFER EQUILIBRIUM; FLUORINATED ALCOHOLS; METAL-FREE; MOLECULAR-WEIGHT; PHENOL-ARENE; CATIONIC-POLYMERIZATION; AROMATIC-COMPOUNDS; HYDROGEN-PEROXIDE; COUPLING REACTION;

D O I：

10.1038/s41570-017-0088

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

1,1,1,3,3,3-Hexafluoroisopropanol (HFIP) has recently become a very popular solvent or additive with applications across the spectrum of chemistry. Analysis shows that it possesses a wide range of interesting and unique properties. In this Perspective, we detail the main uses of HFIP in the natural sciences and disclose the underlying principles that give it such wide appeal. Accordingly, we show the broad usage and beneficial effects in many areas of chemistry.

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页数：12

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