Electrochemical partial fluorination of phenylacetic acids esters and 1-tetralone

被引：17

作者：

Dinoiu, V ^{[1
]}

Fukuhara, T ^{[1
]}

Miura, K ^{[1
]}

Yoneda, N ^{[1
]}

机构：

[1] Hokkaido Univ, Div Mol Chem, Grad Sch Engn, Sapporo, Hokkaido 0608628, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 121卷 / 02期

基金：

日本学术振兴会;

关键词：

electrochemical partial fluorination; phenylacetic acids esters; amine-HF complexes;

D O I：

10.1016/S0022-1139(03)00037-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anodic oxidation of some benzyl derivatives (phenylacetic acids esters) 1, and 1-tetralone 4, using ammonium fluorides or ammonium tetrafluoroborate as fluorine sources and supporting electrolytes and CH2Cl2 as solvent, allowed the introduction of a fluorine atom in the alpha position of an electron withdrawing group via carbocation (C), (ECBECN mechanism). (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：227 / 231

页数：5

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