Dibenzophosphaborin:: A hetero-π-conjugated molecule with fluorescent properties based on intramolecular charge transfer between phosphorus and boron atoms

被引：86

作者：

Agou, T ^{[1
]}

Kobayashi, J ^{[1
]}

Kawashima, T ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 20期

关键词：

D O I：

10.1021/ol051537q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

graph The first dibenzo-1,4-phosphaborins were synthesized and characterized by X-ray crystallographic analysis. The phosphaborins exhibited UV/vis absorption derived from intramolecular charge transfer from the phosphorus atom to the boron atom. The phosphaborins showed different fluorescent properties depending on the substituents on the phosphorus atom.

引用

页码：4373 / 4376

页数：4

共 19 条

[1] Treatment of electronic excitations within the adiabatic approximation of time dependent density functional theory
Bauernschmitt, R
Ahlrichs, R
[J]. CHEMICAL PHYSICS LETTERS, 1996, 256 (4-5) : 454 - 464
[2] Molecular excitation energies to high-lying bound states from time-dependent density-functional response theory: Characterization and correction of the time-dependent local density approximation ionization threshold
Casida, ME
Jamorski, C
Casida, KC
Salahub, DR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) : 4439 - 4449
[3] Connecting π-chromophores by σ-P-P bonds:: New type of assemblies exhibiting σ-π-conjugation
Fave, C
Hissler, M
Kárpáti, T
Rault-Berthelot, J
Deborde, V
Toupet, L
Nyulászi, L
Reau, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) : 6058 - 6063
[4] Frisch M., 2016, Gaussian, V16
[5] Linear organic π-conjugated systems featuring the heavy Group 14 and 15 elements
Hissler, M
Dyer, PW
Réau, R
[J]. COORDINATION CHEMISTRY REVIEWS, 2003, 244 (1-2) : 1 - 44
[6] N-METHYL-B-MESITYLDIBENZO-1,4-AZABORININE - THE 1ST EXPERIMENTAL STRUCTURE OF A 1,4-AZABORININE DERIVATIVE
KRANZ, M
HAMPEL, F
CLARK, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) : 1247 - 1248
[7] KUZNETSOV VA, 1990, ZH OBSHCH KHIM+, V60, P2505
[8] NEW HETEROAROMATIC COMPOUNDS .9. SOME 10,9-BORAZAROANTHRACENES
MAITLIS, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JAN): : 425 - &
[9] NESTEROVA SV, 1988, ZH OBSHCH KHIM+, V58, P1296
[10] NEW COUMARIN DYES WITH RIGIDIZED STRUCTURE FOR FLASHLAMP-PUMPED DYE LASERS
REYNOLDS, GA
DREXHAGE, KH
[J]. OPTICS COMMUNICATIONS, 1975, 13 (03) : 222 - 225

← 1 2 →