Seasonal variation, formation mechanisms and potential sources of PM2.5 in two typical cities in the Central Plains Urban Agglomeration, China

被引：71

作者：

Liu, Huanjia ^{[1
,2
]}

Tian, Hezhong ^{[1
,2
]}

Zhang, Kai ^{[3
]}

Liu, Shuhan ^{[1
,2
]}

Cheng, Ke ^{[4
]}

Yin, Shasha ^{[5
]}

Liu, Yongli ^{[4
]}

Liu, Xiangyang ^{[1
,2
]}

Wu, Yiming ^{[1
,2
]}

Liu, Wei ^{[1
,2
]}

Bai, Xiaoxuan ^{[1
,2
]}

Wang, Yong ^{[1
,2
]}

Shao, Panyang ^{[1
,2
]}

Luo, Lining ^{[1
,2
]}

Lin, Shumin ^{[1
,2
]}

Chen, Jing ^{[1
,2
]}

Liu, Xingang ^{[1
,2
]}

机构：

[1] Beijing Normal Univ, State Key Joint Lab Environm Simulat & Pollut Con, Sch Environm, Beijing 100875, Peoples R China

[2] Beijing Normal Univ, Ctr Atmospher Environm Studies, Beijing 100875, Peoples R China

[3] Univ Texas Hlth Sci Ctr Houston, Sch Publ Hlth, Dept Epidemiol Human Genet & Environm Sci, Houston, TX 77030 USA

[4] Henan Normal Univ, Henan Key Lab Environm Pollut Control, Key Lab Yellow River & Huai River Water Environm, Sch Environm,Minist Educ, Xinxiang 453007, Peoples R China

[5] Zhengzhou Univ, Res Inst Environm Sci, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

SCIENCE OF THE TOTAL ENVIRONMENT | 2019年 / 657卷

基金：

中国国家自然科学基金;

关键词：

Zhengzhou-Xinxiang region; PM2.5; Chemical components; Formation mechanisms; Seasonal variation; Geographical origin; YANGTZE-RIVER DELTA; RESOLUTION EMISSION INVENTORY; PRIMARY AIR-POLLUTANTS; SOURCE APPORTIONMENT; CHEMICAL-COMPOSITION; CARBONACEOUS AEROSOLS; HAZE EVENTS; ORGANIC AEROSOLS; PM2.5-BOUND PAHS; SICHUAN BASIN;

D O I：

10.1016/j.scitotenv.2018.12.068

中图分类号：

X [环境科学、安全科学];

学科分类号：

083001 [环境科学];

摘要：

In order to probe the seasonal variation, formation mechanisms as well as geographical origins of fine particles and its chemical components in two cities (Zhengzhou, ZZ and Xinxiang, XX) in Central Plains Urban Agglomeration, daily PM2.5 aerosol samples were collected for four consecutive seasons during 2017-2018. The annual average concentrations of PM2.5 (particulate matter with an aerodynamic diameter smaller than 2.5 mu m) were calculated at 70.5 +/- 50.8 and 69.0 +/- 463 mu g m(-3) at ZZ and XX, respectively. Daily ambient PM2.5 concentrations ranged from 18.2 to 303.0 mu g m(-1), among which >81% of the total sampling days exceeded the National Ambient Air Quality Standard of China (NAAQS, 35 mu g m(-3) as an annual average). Additionally, concentrations of PM2.5 and its major chemical components were seasonally dependent, usually with the highest mass concentration in winter. Compared with previous studies, higher NO3-/SO42- were observed in this study depicted that air pollution caused by motor vehicle exhaust cannot be ignored. OC concentration was higher at ZZ than XX during sampling campaign likely partially caused by larger number of motor vehicles, chemical pesticide and solvent used in ZZ. Both homogeneous and heterogeneous reactions played an important role in the formation of nitrate, while heterogeneous reactions dominated the formation of sulfate. We also found a faster increase in nitrate than in sulfate during the evolution of haze. The characteristics of long-range transportation of PM2.5 and its major chemical components and gaseous precursors were observed at both sites through back trajectories and WPSCF analysis, suggesting the complexity of air pollution and the multi-influence among cities. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：657 / 670

页数：14

共 72 条

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O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry [J].