Interatomic potentials of group IIB atoms (ground state)

被引:17
作者
Ceccherini, S
Moraldi, M
机构
[1] Univ Florence, Dipartimento Fis, Unita Ric Firenze, Ist Nazl Fis Mat, I-50125 Florence, Italy
[2] Ist Nazl Fis Mat, Unita Ric Firenze, I-50125 Florence, Italy
关键词
D O I
10.1016/S0009-2614(01)00203-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Excitation and fluorescence spectra of group IIB atoms (Hg, Cd, Zn) have been extensively measured in the last years. From these measurements dependable values for potential parameters like well-depth and vibrational frequency for the ground electronic state have been derived with a high degree of accuracy. A determination of the equilibrium distance for Hg is also available. For Cd and Zn, the equilibrium distances are not known, though. Here we propose to use low-density viscosity measurements together with the spectroscopic data to give an estimate of these distances. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:386 / 390
页数:5
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