Synthesis, Swelling, and Exfoliation of Microporous Lamellar Titanosilicate AM-4

被引：23

作者：

Casado, Clara ^{[1
]}

Ambroj, Diego ^{[1
]}

Mayoral, Alvaro ^{[2
]}

Vispe, Eugenio ^{[3
,4
]}

Tellez, Carlos ^{[1
]}

Coronas, Joaquin ^{[1
]}

机构：

[1] Univ Zaragoza, Chem & Environm Engn Dept, Zaragoza 50018, Spain

[2] Univ Zaragoza, Nanosci Inst Aragon, Lab Microscopia Avanzada, Zaragoza 50018, Spain

[3] Univ Zaragoza, Dept Organ Chem, E-50009 Zaragoza, Spain

[4] Univ Zaragoza, Inst Univ Catalisis Homogenea, E-50009 Zaragoza, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 14期

关键词：

Intercalations; Layered compounds; Adsorption; Organic-inorganic hybrid composites; Zeolite analogues; TITANIUM-NIOBIUM-SILICATES; NANOCOMPOSITE MEMBRANES; NENADKEVICHITE; COMPLEXES; CATALYSIS; ZEOLITE; JDF-L1; AMH-3;

D O I：

10.1002/ejic.201100152

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

AM-4 is a layered porous titanosilicate built from TiO(6) and SiO(4) polyhedra. An improved synthesis of AM-4 crystals enabling control of particle size by secondary growth and reducing synthesis time is presented. A new material, UZAR-S2, has been obtained by exfoliation of the smaller AM-4. The exfoliation consists of proton exchange with acetic acid, intercalation with nonylamine, and final activation by washing with HCl/water/ethanol. Besides XRD, TEM, N(2) adsorption, FTIR, and UV/Vis characterization highlighting the delaminated character of UZAR-S2, CO(2) adsorption was also measured.

引用

页码：2247 / 2253

页数：7

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