Preparation and reactivity of some functionalized halomethylzinc carbenoids.

被引：8

作者：

Charette, AB ^{[1
]}

Beauchemin, A ^{[1
]}

Marcoux, JF ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(98)80012-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various mixed diorganozinc reagents were prepared by the irradiation of diethylzinc and functionalized alkyl iodides. These species were shown to react with dihalomethane to form zinc carbenoids in a highly regioselective manner. In some cases, the latter reagents proved to be effective cyclopropanating reagents. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：33 / 36

页数：4

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