Magnetic properties of nano-particles of Au, Pd and Pd/Ni alloys

被引:19
作者
Hori, H [1 ]
Teranishi, T [1 ]
Taki, M [1 ]
Yamada, S [1 ]
Miyake, M [1 ]
Yamamoto, Y [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan
关键词
nanoparticles; quantum size effect; superparamagnetism; spin correlations;
D O I
10.1016/S0304-8853(00)01393-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Well-characterized nanometer sized metal particles (nano-particle) with quite narrow diameter distribution have been synthesized by chemical method and their magnetic properties were investigated systematically using SQUID magnetometer and ESR spectrometer. Au and Pd nano-particles display the ferromagnetism contrary to the para- and diamagnetism in their bulk state. Moreover, the magnetization of Pd particles has been measured as a function of particle diameter and showed threshold size of about 3 nm. This result suggests the existence of a critical size changing from atomic to metallic spin correlation. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1910 / 1911
页数:2
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