Highly active metal-acid bifunctional catalyst system for hydrogenolysis of glycerol under mild reaction conditions

被引：219

作者：

Kusunoki, Y ^{[1
]}

Miyazawa, T ^{[1
]}

Kunimori, K ^{[1
]}

Tomishige, K ^{[1
]}

机构：

[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan

来源：

CATALYSIS COMMUNICATIONS | 2005年 / 6卷 / 10期

关键词：

glycerol; hydrogenolysis; metal; acid; ion exchange resin; propylene glycol;

D O I：

10.1016/j.catcom.2005.06.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Combination of active carbon supported Ru catalyst with a cation exchange resin (Amberlyst 15) exhibited much higher activity in glycerol hydrogenolysis under mild reaction conditions such as 393 K and 4 MPa H-2, than other metal-acid bifunctional catalyst systems using various zeolites, sulfated zirconia, H2WO4, and liquid H2SO4. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：645 / 649

页数：5

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