A new class of luminescent polypyridine complexes of rhenium(I) containing cis-carbonyl ligands

被引：32

作者：

Schutte, E ^{[1
]}

Helms, JB ^{[1
]}

Woessner, SM ^{[1
]}

Bowen, J ^{[1
]}

Sullivan, BP ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 11期

关键词：

D O I：

10.1021/ic971199s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of long-lived luminescent complexes of the type cis-Re-I(CO)(2)(N-N)(P-P)(+) (where N-N is a chelate polypyridine ligand and P-P is a chelate phosphine) has been prepared. The new Re excited states are of extraordinary stability and exhibit redshifted spectral responses relative to the well-studied fac-Re(bpy)(CO)(3)L(+70) series (L is a variety of neutral and anionic ligands). Of primary interest are their extremely long lifetimes in CH2Cl2 solution, which could be a consequence of an energy gap law different from that of the tricarbonyl complexes.

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页码：2618 / +

页数：3

相关论文

共 36 条

[1] NONRADIATIVE ELECTRONIC RELAXATION UNDER COLLISION-FREE CONDITIONS [J].

AVOURIS, P ;

GELBART, WM ;

ELSAYED, MA .

CHEMICAL REVIEWS, 1977, 77 (06) :793-833

[2] RHENIUM CARBONYL-COMPLEXES WITH BIS(DIPHENYL PHOSPHINO)METHANE - X-RAY CRYSTAL-STRUCTURE OF [REBR(CO)2(PH2PCH2PPH2)(PH2PCH2P'PH2).0.43[REBR(CO)2(PH2PCH2PPH2)(PH2PCH2P(O)PH2)] [J].

CARRIEDO, GA ;

RODRIGUEZ, ML ;

GARCIAGRANDA, S ;

AGUIRRE, A .

INORGANICA CHIMICA ACTA, 1990, 178 (01) :101-106

[3] APPLICATION OF THE ENERGY-GAP LAW TO NONRADIATIVE, EXCITED-STATE DECAY [J].

CASPAR, JV ;

MEYER, TJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (06) :952-957

[4] SYNTHETIC ROUTES TO LUMINESCENT 2,2'-BIPYRIDYL COMPLEXES OF RHENIUM - PREPARATION AND SPECTRAL AND REDOX PROPERTIES OF MONO(BIPYRIDYL) COMPLEXES OF RHENIUM(III) AND RHENIUM(I) [J].

CASPAR, JV ;

SULLIVAN, BP ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1984, 23 (14) :2104-2109

[5]

CASPAR JV, 1983, THESIS U N CAROLINA

[6] Tricarbonyl(1,1O-phenanthroline)(imidazole)rhenium(I): A powerful photooxidant for investigations of electron tunneling in proteins [J].

Connick, WB ;

DiBilio, AJ ;

Hill, MG ;

Winkler, JR ;

Gray, HB .

INORGANICA CHIMICA ACTA, 1995, 240 (1-2) :169-173

[7] SPECTROSCOPIC PROPERTIES OF (ND)10 TRANSITION-METAL COMPLEXES [J].

CROSBY, GA ;

HIGHLAND, RG ;

TRUESDELL, KA .

COORDINATION CHEMISTRY REVIEWS, 1985, 64 (MAY) :41-52

[8] SPATIALLY ISOLATED REDOX ORBITALS - AN UPDATE [J].

DEARMOND, MK ;

HANCK, KW ;

WERTZ, DW .

COORDINATION CHEMISTRY REVIEWS, 1985, 64 (MAY) :65-81

[9] SYNTHESIS AND SPECTRAL FEATURES OF SOME CATIONIC MANGANESE(I) AND RHENIUM(I) TRICARBONYL COMPLEXES [J].

EDWARDS, DA ;

MARSHALSEA, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 131 (01) :73-91

[10] RADIATIONLESS TRANSITIONS IN MOLECULES [J].

FREED, KF .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (02) :74-80

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