Theory of capillary electrochromatograpy

被引:110
作者
Bartle, KD [1 ]
Myers, P [1 ]
机构
[1] Univ Leeds, Sch Chem, Woodhouse Lane, Leeds LS2 9JT, W Yorkshire, England
关键词
electrochromatography; electroosmotic flow; mobile phase composition; temperature effects; band broadening;
D O I
10.1016/S0021-9673(01)00709-9
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The present state of the theory of capillary electrochromatography (CEC) is reviewed. Emphasis is placed on electroosmosis and the electrical double layer, and the generally good understanding of the factors affecting the electroosmotic flow in CEC columns. The relation of CEC to other electrically driven separations are described, along with band broadening, and the influence of column temperature in CEC. The thoretical potential of CEC is assessed from the standpoint of current and future column technology, and likely future application areas are described. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码:3 / 23
页数:21
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