Bis(iodozincio)methane - preparation, structure, and reaction

被引：58

作者：

Matsubara, S ^{[1
]}

Oshima, K ^{[1
]}

Utimoto, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 617卷 / 01期

关键词：

dimetal; zinc; palladium; titanium; EXAFS;

D O I：

10.1016/S0022-328X(00)00546-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(iodozincio)methane was prepared from diiodomethane and zinc in the presence of a catalytic amount of lead. The compound showed a high potential as an organic synthetic reagent. The reaction with carbonyl compounds proceeded to give methylenated products. The reagent also reacted with a couple of electrophiles. A structural study was also examined. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：39 / 46

页数：8

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