Asymmetric bis(alkoxycarbonylation) reaction of cyclic olefins catalyzed by palladium in the presence of copper(I) triflate

被引：10

作者：

Aratani, Takahiro ^{[1
]}

Tahara, Kenji ^{[1
]}

Takeuchi, Susumu ^{[1
]}

Ukaji, Yutaka ^{[1
]}

Inomata, Katsuhiko ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Mat Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 11期

关键词：

D O I：

10.1246/cl.2007.1328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium-catalyzed asymmetric bis(alkoxycarbonylation) reaction of cyclic olefins in the presence of copper(l) triflate was achieved by using a chiral bioxazoline ligand under normal pressure of carbon monoxide and oxygen to give the corresponding optically active cis-dicarboxylates with enantio-selectivities up to 94% ee. The carbonylated product was well applied to the synthesis of a biologically active hexahydrobenz-[e]isoindole derivative.

引用

页码：1328 / 1329

页数：2

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