Lipase-catalysed chemoselective monoacetylation of hydroxyalkylphenols and chemoselective removal of a single acetyl group from their diacetates

被引：37

作者：

Allevi, P ^{[1
]}

Ciuffreda, P ^{[1
]}

Longo, A ^{[1
]}

Anastasia, M ^{[1
]}

机构：

[1] Univ Milan, Dept Med Chem & Biochem, I-20133 Milan, Italy

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 16期

关键词：

D O I：

10.1016/S0957-4166(98)00285-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It was demonstrated that Pseudomonas cepacia PS lipase adsorbed on Celite, has the ability to catalyse: the chemoselective monoacetylation of various hydroxyalkylphenols or the chemoselective removal of a single acetyl group from the corresponding acetate. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2915 / 2924

页数：10

共 29 条

[1] ENZYMATIC RESOLUTION OF (R)-(E)-4-HYDROXYALK-2-ENALS AND (S)-(E)-4-HYDROXYALK-2-ENALS RELATED TO LIPID-PEROXIDATION [J].

ALLEVI, P ;

ANASTASIA, M ;

CAJONE, F ;

CIUFFREDA, P ;

SANVITO, AM .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (18) :5000-5002

[2] A SIMPLE ONE POT SYNTHESIS OF AROMATIC STEROIDAL AND NONSTEROIDAL C-GLUCOSIDES VIA O-GLUCOSIDES [J].

ALLEVI, P ;

ANASTASIA, M ;

CIUFFREDA, P ;

SANVITO, AM ;

SCALA, A .

CHEMISTRY AND PHYSICS OF LIPIDS, 1992, 63 (03) :179-189

[3] SELECTIVE ENZYMATIC-HYDROLYSIS OF PHENOLIC ACETATES [J].

BASAVAIAH, D ;

RAJU, SB .

SYNTHETIC COMMUNICATIONS, 1994, 24 (04) :467-473

[4] RESOLUTION OF (+/-)-TRANS-SOBREROL BY LIPASE PS-CATALYZED TRANSESTERIFICATION AND EFFECTS OF ORGANIC-SOLVENTS ON ENANTIOSELECTIVITY [J].

BOVARA, R ;

CARREA, G ;

FERRARA, L ;

RIVA, S .

TETRAHEDRON-ASYMMETRY, 1991, 2 (09) :931-938

[5] Selective monoacetylation of unsymmetrical diols catalyzed by silica gel-supported sodium hydrogen sulfate [J].

Breton, GW .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (25) :8952-8954

[6]

GREENE TW, 1991, PROTECTIVE GROUPS OR, P90

[7]

GUPTA RS, 1987, ANTI-CANCER DRUG DES, V2, P13

[8] Selective monoacetylation of diol compounds by Aspergillus niger lipase [J].

Hsiao, KF ;

Yang, FL ;

Wu, SH ;

Wang, KT .

BIOTECHNOLOGY LETTERS, 1996, 18 (11) :1277-1282

[9]

IINUMA M, 1987, CHEM PHARM BULL, V35, P660

[10] LIPASE-CATALYZED STEREOSELECTIVE ACYLATION OF [1,1'-BINAPHTHYL]-2,2'-DIOL AND DEACYLATION OF ITS ESTERS IN AN ORGANIC-SOLVENT [J].

INAGAKI, M ;

HIRATAKE, J ;

NISHIOKA, T ;

ODA, J .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1989, 53 (07) :1879-1884

← 1 2 3 →