Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene

被引：38

作者：

Basuli, F

Watson, LA

Man, JCH

Mindiola, DJ ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

DALTON TRANSACTIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b311748k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the terminal titanium - phosphinidene (Nacnac) Ti=PMes*((CH2Bu)-Bu-t) (Nacnac(-) = [2,6-(Pr2C6H3)-Pr-i] NC( CH3) CHC(CH3) N[2,6-(Pr2C6H3)-Pr-i], Mes(*-) = 2,4,6-(Bu3C6H2)-Bu-t) with (CNBu)-Bu-t and N2CPh2, in pentane at - 35 degreesC, affords eta(2)-(N,C)- phosphaazaallene and phosphinylimide complexes, respectively.

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页码：4228 / 4229

页数：2

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