Controlling length of gold nanowires with large-scale: X-ray absorption spectroscopy approaches to the growth process

被引:38
作者
Chen, Hao Ming [1 ]
Liu, Ru-Shi [1 ]
Asakura, Kiyotaka [2 ]
Jang, Ling-Yun [3 ]
Lee, Jyh-Fu [3 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[2] Hokkaido Univ, Ctr Catalysis Res, Sapporo, Hokkaido, Japan
[3] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
关键词
D O I
10.1021/jp0770615
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By utilizing the X-ray absorption approach, the gold ions evolving from the Au-Cl complex to Au rods have been elucidated. The theoretical simulation of X-ray absorption spectra further revealed the evolution of gold and concluded that ultrafine small clusters of gold (Au-13) formed after a reducing agent was added to the growth solution. A redesigned seed-assisted growth method, a serial addition of growth solution, was employed to achieve the goal of the consecutive support of gold. The development approach was found to successfully fabricate ID gold nanorods/wires with a tunable size from 50 nm to 1.7 mu m.
引用
收藏
页码:18550 / 18557
页数:8
相关论文
共 95 条
[1]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[2]   Sensitivity of Pt x-ray absorption near edge structure to the morphology of small Pt clusters [J].
Ankudinov, AL ;
Rehr, JJ ;
Low, JJ ;
Bare, SR .
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (05) :1911-1919
[3]   Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure [J].
Ankudinov, AL ;
Ravel, B ;
Rehr, JJ ;
Conradson, SD .
PHYSICAL REVIEW B, 1998, 58 (12) :7565-7576
[4]  
[Anonymous], 1972, CRYSTAL CHEM PHYS ME
[5]   EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE OF SMALL CU AND NI CLUSTERS - BINDING-ENERGY AND BOND-LENGTH CHANGES WITH CLUSTER SIZE [J].
APAI, G ;
HAMILTON, JF ;
STOHR, J ;
THOMPSON, A .
PHYSICAL REVIEW LETTERS, 1979, 43 (02) :165-169
[6]   Limits and advantages of x-ray absorption near edge structure for nanometer scale metallic clusters [J].
Bazin, D ;
Rehr, JJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (45) :12398-12402
[7]   Numerical simulation of the platinum L-III edge white line relative to nanometer scale clusters [J].
Bazin, D ;
Sayers, D ;
Rehr, JJ ;
Mottet, C .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (27) :5332-5336
[8]   Multiple scattering calculation of absorption spectrum and diffraction calculation: Application to nanometer scale copper metallic particle [J].
Bazin, D ;
Bensaddik, A ;
Briois, V ;
Sainctavit, P .
JOURNAL DE PHYSIQUE IV, 1996, 6 (C4) :481-485
[9]   Structure and bonding of gold metal clusters, colloids, and nanowires studied by EXAFS, XANES, and WAXS [J].
Benfield, RE ;
Grandjean, D ;
Kröll, M ;
Pugin, R ;
Sawitowski, T ;
Schmid, G .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (10) :1961-1970
[10]   Design of a surface alloy catalyst for steam reforming [J].
Besenbacher, F ;
Chorkendorff, I ;
Clausen, BS ;
Hammer, B ;
Molenbroek, AM ;
Norskov, JK ;
Stensgaard, I .
SCIENCE, 1998, 279 (5358) :1913-1915