Reversible binding of dioxygen by a non-transition-metal complex

被引：116

作者：

Abakumov, GA ^{[1
]}

Poddel'sky, AI ^{[1
]}

Grunova, EV ^{[1
]}

Cherkasov, VK ^{[1
]}

Fukin, GK ^{[1
]}

Kurskii, YA ^{[1
]}

Abakumova, LG ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 18期

关键词：

antimony; N; O ligands; oxo ligands; oxygen; peroxides;

D O I：

10.1002/anie.200462503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxygen binds reversibly to the non-transition-metal complex 1 to form the spiroendoperoxide 2 (see scheme). Complexes 1 and 2 were characterized by NMR, IR, and UV/Vis spectroscopies, and their molecular structures were determined by X-ray crystallography. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2767 / 2771

页数：5

共 34 条

[1] NMR study of products of thermal transformation of substituted N-aryl-o-quinoneimines
Abakumov, GA
Druzhkov, NO
Kurskii, YA
Shavyrin, AS
[J]. RUSSIAN CHEMICAL BULLETIN, 2003, 52 (03) : 712 - 717
[2] ABAKUMOV GA, 1982, DOKL AKAD NAUK SSSR+, V266, P361
[3] Reversible binding of oxygen to aromatic compounds
Aubry, JM
Pierlot, C
Rigaudy, J
Schmidt, R
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (09) : 668 - 675
[4] CRYSTAL-STRUCTURE OF 2,2,4,4-TETRAHYDRO-2,2,2,4,4,4-HEXAPHENYL-1,3,2,4-DIOXADISTIBETANE (TRIPHENYLSTIBINE OXIDE DIMER) AND RELATED-COMPOUNDS
BORDNER, J
DOAK, GO
EVERETT, TS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) : 4206 - 4213
[5] Oxidation of tetraaryldistibanes:: syntheses and crystal structures of diarylantimony oxides and peroxides, (R2Sb)2O, (R2Sb)4O6 and (R2SbO)4(O2)2 (R = Ph, o-Tol, p-Tol)
Breunig, H
Krüger, T
Lork, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 648 (1-2) : 209 - 213
[6] Breunig H. J., 1997, ANGEW CHEM, V109, P654
[7] A mu(4)-peroxo complex of antimony: Synthesis and structure of (o-Tol(2)SbO)(4)(O-2)(2)
Breunig, HJ
Kruger, T
Lork, E
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06): : 615 - 617
[8] TAUTOMERIC CATECHOLATE-SEMIQUINONE INTERCONVERSION VIA METAL-LIGAND ELECTRON-TRANSFER - STRUCTURAL, SPECTRAL, AND MAGNETIC-PROPERTIES OF (3,5-DI-TERT-BUTYLCATECHOLATO)-(3,5-DI-TERT-BUTYLSEMIQUINONE)(BIPYRIDYL)COBALT(III), A COMPLEX CONTAINING MIXED-VALENCE ORGANIC-LIGANDS
BUCHANAN, RM
PIERPONT, CG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (15) : 4951 - 4957
[9] IRON AND COBALT LACUNAR COMPLEXES AS DIOXYGEN CARRIERS
BUSCH, DH
ALCOCK, NW
[J]. CHEMICAL REVIEWS, 1994, 94 (03) : 585 - 623
[10] VANADIUM PEROXIDE COMPLEXES
BUTLER, A
CLAGUE, MJ
MEISTER, GE
[J]. CHEMICAL REVIEWS, 1994, 94 (03) : 625 - 638

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