Selective removal of cesium from acid solutions with immobilized copper ferrocyanide

被引:44
作者
Clarke, TD [1 ]
Wai, CM [1 ]
机构
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
关键词
D O I
10.1021/ac971138b
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Copper ferrocyanide can be immobilized on Chelex-20, a technical grade chelating resin, for selective removal of cesium from neutral to acidic solutions. The immobilized copper ferrocyanide is much easier to handle than the copper ferrocyanide powder in extraction and separation of cesium from aqueous solutions. In the presence of a reducing agent such as hydrazine, the immobilized copper ferrocyanide resin is able to remove 98% of the cesium from a simulated acid waste solution in one cycle of batch experiments. The resin shows promising properties for remediation of acidic nuclear wastes and for concentration of Cs-137 from environmental samples for quantitative analysis.
引用
收藏
页码:3708 / 3711
页数:4
相关论文
共 9 条
[1]  
BEKLEMISHEV MK, 1996, SEPARATION TECHNIQUE, P47
[2]  
*BIOR LAB, 1986, B BIOR LAB, V1224
[3]   ADSORPTION OF MONOVALENT IONS ON ZINC FERROCYANIDE [J].
GANZERLI.MT ;
MELONI, S ;
MAXIA, V .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (04) :1427-&
[4]  
GANZERLIVALENTI.MT, 1986, J RADIOANAL NUCL CHE, V102, P99
[5]  
HUCKLE W, 1950, STRUCTURAL CHEM INOR, V1
[6]   SYNTHETIC INORGANIC ION-EXCHANGERS .2. SALTS OF HETEROPOLYACIDS, INSOLUBLE FERROCYANIDES, SYNTHETIC ALUMINOSILICATES AND MISCELLANEOUS EXCHANGERS [J].
PEKAREK, V ;
VESELY, V .
TALANTA, 1972, 19 (11) :1245-&
[7]   EXTRACTION OF CESIUM WITH DERIVATIVES OF CARBORANE INTO NITROBENZENE [J].
RAIS, J ;
PLESEK, J ;
SELUCKY, P ;
KYRS, M ;
KADLECOVA, L .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1991, 148 (02) :349-357
[8]   SOLVENT-EXTRACTION RECOVERY OF BY-PRODUCT CS-137 AND SR-90 FROM HNO3 SOLUTIONS - A TECHNOLOGY REVIEW AND ASSESSMENT [J].
SCHULZ, WW ;
BRAY, LA .
SEPARATION SCIENCE AND TECHNOLOGY, 1987, 22 (2-3) :191-214
[9]  
TUSA E, 1993, WASTE MANAGE, P1693