The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

被引：86

作者：

Kakiuchi, F ^{[1
]}

Sato, T ^{[1
]}

Igi, K ^{[1
]}

Chatani, N ^{[1
]}

Murai, S ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 05期

关键词：

D O I：

10.1246/cl.2001.386

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of a beta C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)(2)(CO)(PPh3)(3) as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.

引用

页码：386 / 387

页数：2

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