(NC5H12)2•Zn3(HPO3)4:: A low-density framework built up from a fully connected (3,4) net of ZnO4 tetrahedra and HPO3 pseudo pyramids

被引：72

作者：

Harrison, WTA ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2001年 / 160卷 / 01期

关键词：

D O I：

10.1006/jssc.2001.9219

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(NC5H12)2 . Zn-3(HPO3)(4), the first organically templated, three-dimensional zincophosphite framework, is built up from a fully connected (3,4) net of ZnO4 tetrahedra and HPO3 pseudo pyramids, sharing vertices as Zn-O-P bonds. These units self-assemble around the piperidinium templates to result in a low-density anionic framework containing helical columns and 4-ring and 16-ring windows. Crystal data: (NC5H12)(2). Zn-3(HPO3)4, M-r = 688.39, mortoclinic, C2/c (No. 15), a = 16.3351(7) Angstrom, b = 9.2750(4) Angstrom, c = 17.2416(8) Angstrom, beta = 117.987(1)degrees, V = 2306.8 (3) Angstrom (3), Z = 4, R = 0.032, R-w = 0.036. (C) 2001 Academic Press.

引用

页码：4 / 7

页数：4

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