Time-resolved resonance Raman observation of the 2-fluorenylnitrenium ion reaction with guanosine to form a C8 intermediate

被引：36

作者：

Chan, PY ^{[1
]}

Kwok, WM ^{[1
]}

Lam, SK ^{[1
]}

Chiu, P ^{[1
]}

Phillips, DL ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 23期

关键词：

D O I：

10.1021/ja0505651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two CN conjugated bonds in ring 1 of the guanosine moiety. Copyright © 2005 American Chemical Society.

引用

页码：8246 / 8247

页数：2

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