Resorcinol-Templated Synthesis of a Cofacial Terpyridine in Crystalline π-Stacked Columns

被引：22

作者：

Dutta, Saikat ^{[1
]}

Bucar, Dejan-Kresimir ^{[1
]}

MacGillivray, Leonard R. ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 09期

基金：

美国国家科学基金会;

关键词：

SOLID-STATE; COMPLEXES; PHOTODIMERIZATION; MOTIFS;

D O I：

10.1021/ol200532t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A resorcinol achieves a templated stereospecific and near-quantitative synthesis of a cofacial terpyridine in the solid state. The solid-state synthesis occurs in one-dimensional pi-stacked columns with reactivities highly sensitive to peripheral groups attached to the template.

引用

收藏

页码：2260 / 2262

页数：3

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