Template-directed synthesis of aragonite under supramolecular hydrogen-bonded Langmuir monolayers

被引：161

作者：

Litvin, AL

Valiyaveettil, S

Kaplan, DL

Mann, S

机构：

[1] GEOCENTERS INC,NATICK,MA 01760

[2] TUFTS UNIV,CTR BIOTECHNOL,MEDFORD,MA 02155

[3] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY

[4] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 02期

关键词：

D O I：

10.1002/adma.19970090205

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design of supramolecular templates to direct the synthesis of organized inorganic materials is illustrated for aragonite (CaCO3), which is metastable under ambient conditions but found in gall-stones, fish otoliths, etc. Spreading of the template 5-hexadecyloxyisophthalic acid at the air/water interface is shown to result in the specific nucleation of aragonite from supersaturated calcium bicarbonate solution without additives.

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页码：124 / 127

页数：4

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