High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries

被引:352
作者
Hassoun, Jusef
Panero, Stefania
Simon, Patrice
Taberna, Pierre Louis
Scrosati, Bruno
机构
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[2] Univ Toulouse 3, CIRIMAT, UMR 5085, F-31062 Toulouse 4, France
关键词
D O I
10.1002/adma.200602035
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ni3Sn4 intermetallic electrodes prepared into a revolutionary nanostructure. obtained by electrodeposition on a nanoarchitectured Cu substrate, are described. This structure controls the volume stress that accompanies the electrochemical process yielding a performance rarely observed with lithium metal storage electrodes. The new electrode shows impressive electrochemical behavior and cycles in lithium cells for more than 200 cycles (figure shows electrode after cycling) with a stable high capacity.
引用
收藏
页码:1632 / +
页数:5
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