{2Fe3S} clusters related to the di-iron sub-site of the H-centre of all-iron hydrogenases

被引:116
作者
Razavet, M [1 ]
Davies, SC [1 ]
Hughes, DL [1 ]
Pickett, CJ [1 ]
机构
[1] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
关键词
D O I
10.1039/b102244j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first synthetic {2Fe3S} clusters structurally related to the sub-site of the H-centre of the all-iron hydrogenases are described: tripodal dithiolate thioether ligands allow the synthesis of di-iron pentacarbonyls with differential (2:3) S ligation of the Fe atoms.
引用
收藏
页码:847 / 848
页数:2
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