Imaging planar tetragonal sheets in rhombohedral Na0.5Bi0.5TiO3 using transmission electron microscopy

被引:48
作者
Beanland, R. [1 ]
Thomas, P. A. [1 ]
机构
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
Na0.5Bi0.5TiO3 (NBT); Transmission electron microscopy (TEM); Electron diffraction; Ferroelectric ceramics; Crystal defects; PHASE-TRANSITIONS; DIFFRACTION; PEROVSKITES; CERAMICS; SYSTEM;
D O I
10.1016/j.scriptamat.2011.05.031
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Planar nanometre-scale inclusions in single-crystal Na0.5Bi0.5TiO3 have been investigated using transmission electron microscopy at room temperature. In diffraction patterns, they give rise to weak extra spots and diffuse contrast. Here we show that they are visible in diffraction contrast images, giving a new route to directly observe subtly different structures in perovskites. Visibility is determined by their structure and diffraction vector. We show that single-crystal a(-)a(-)a(-) Na0.5Bi0.5TiO3 contains an inhomogeneous distribution of nanometre-scale {0 0 1} platelets of tetragonal a(0)a(0)c(+) material. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:440 / 443
页数:4
相关论文
共 19 条
[1]   Monoclinic crystal structure of polycrystalline Na0.5Bi0.5TiO3 [J].
Aksel, Elena ;
Forrester, Jennifer S. ;
Jones, Jacob L. ;
Thomas, Pam A. ;
Page, Katharine ;
Suchomel, Matthew R. .
APPLIED PHYSICS LETTERS, 2011, 98 (15)
[2]   The rhombohedral phase with incommensurate modulation in Na1/2Bi1/2TiO3 [J].
Balagurov, AM ;
Koroleva, EY ;
Naberezhnov, AA ;
Sakhnenko, VP ;
Savenko, BN ;
Ter-Oganessian, NV ;
Vakhrushev, SB .
PHASE TRANSITIONS, 2006, 79 (1-2) :163-173
[3]   Structure of planar defects in tilted perovskites [J].
Beanland, Richard .
ACTA CRYSTALLOGRAPHICA SECTION A, 2011, 67 :191-199
[4]   Reinvestigation of phase transitions in Na0.5Bi0.5TiO3 by TEM.: Part I:: First order rhombohedral to orthorhombic phase transition [J].
Dorcet, V. ;
Trolliard, G. ;
Boullay, P. .
CHEMISTRY OF MATERIALS, 2008, 20 (15) :5061-5073
[5]   A transmission electron microscopy study of the A-site disordered perovskite Na0.5Bi0.5TiO3 [J].
Dorcet, V. ;
Trolliard, G. .
ACTA MATERIALIA, 2008, 56 (08) :1753-1761
[6]   Structural and dielectric studies of the Na0.5Bi0.5TiO3-BiFeO3 system [J].
Dorcet, V. ;
Marchet, P. ;
Trolliard, G. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) :4371-4374
[7]   The structural origin of the antiferroelectric properties and relaxor behavior of Na0.5Bi0.5TiO3 [J].
Dorcet, V. ;
Trolliard, G. ;
Boullay, P. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2009, 321 (11) :1758-1761
[8]   Influence of Mn Doping on the Structure and Properties of Na0.5Bi0.5TiO3 Single Crystals [J].
Ge, Wenwei ;
Li, Jiefang ;
Viehland, Dwight ;
Luo, Haosu .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (05) :1372-1377
[9]   CLASSIFICATION OF TILTED OCTAHEDRA IN PEROVSKITES [J].
GLAZER, AM .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1972, B 28 (NOV15) :3384-&
[10]   SIMPLE WAYS OF DETERMINING PEROVSKITE STRUCTURES [J].
GLAZER, AM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1975, 31 (NOV1) :756-762