(Phosphacyclopentadienyl)indium(I) derivatives:: Synthesis and X-ray crystal structure of [In(η5-P3C2But2)]

被引：40

作者：

Callaghan, C ^{[1
]}

Clentsmith, GKB ^{[1
]}

Cloke, FGN ^{[1
]}

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

Vickers, DM ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 04期

关键词：

D O I：

10.1021/om980877v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Go-condensation of indium vapor and tertbutylphosphaethyne at 77 K yields two new, volatile In(I) complexes: [In(eta(5)-P3C2Bu2t)] (1) and [In(eta(5)-P2C3Bu3t)] (2). A single-crystal X-ray diffraction experiment on I reveals a discrete molecular structure, involving half-sandwich coordination of the P3C2Bu2t ring around the indium center. 1 may be independently prepared by treating InI with the newly synthesized, base-free ligand salt K(P3C2Bu2t).

引用

页码：793 / 795

页数：3

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