Palladium-catalyzed asymmetric 1,3-dipolar cycloaddition of nitrones to olefins

被引：68

作者：

Hori, K ^{[1
]}

Kodama, H ^{[1
]}

Ohta, T ^{[1
]}

Furukawa, I ^{[1
]}

机构：

[1] DOSHISHA UNIV,FAC ENGN,DEPT MOL SCI & TECHNOL,TANABE,KYOTO 61003,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 33期

关键词：

D O I：

10.1016/0040-4039(96)01284-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric 1,3-dipolar cycloaddition of nitrone 2 to olefin 1 was catalyzed by chiral phosphine-palladium complexes to give isoxazolidine 3 in high yield with high enantioselectivity up to 91% ee. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5947 / 5950

页数：4

共 28 条

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[5] CHROMIUM AND TUNGSTEN PENTACARBONYL GROUPS AS REACTIVITY AND SELECTIVITY AUXILIARIES IN [3+2] CYCLOADDITION OF ALKYNYL FISCHER CARBENE COMPLEXES WITH N-ALKYL NITRONES
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[6] ASYMMETRIC DIELS-ALDER CYCLO-ADDITION REACTIONS WITH CHIRAL ALPHA, BETA-UNSATURATED N-ACYLOXAZOLIDINONES
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[7] TRANSITION-METAL-CATALYZED ASYMMETRIC 1,3-DIPOLAR CYCLOADDITION REACTIONS BETWEEN ALKENES AND NITRONES
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