Synthesis of the star-shaped copolymer of ε-caprolactone and L-lactide from a cyclotriphosphazene core

被引：23

作者：

Cui, YJ ^{[1
]}

Tang, XZ ^{[1
]}

Huang, XB ^{[1
]}

Chen, Y ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, State Key Lab Composite Mat, Shanghai 200240, Peoples R China

来源：

BIOMACROMOLECULES | 2003年 / 4卷 / 06期

关键词：

D O I：

10.1021/bm034237+

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Hexakis[p-(hydroxylmethyl)phenoxy]cyclotriphosphazene was synthesized by the reaction of hexachlorocyclotriphosphazene with the sodium salt of 4-hydroxybenzaldehyde and subsequent reduction of aldehyde Groups to alcohol groups by using sodium borohydride. This compound was employed in initiating the ring-opening polymerization of epsilon-caprolactone and L-lactide to produce star-shaped poly(L-lactide) (PLA), poly(epsilon-caprolactone) (PCL), and their block copolymer with cyclophosphazene cores. H-1 NMR and GPC analysis showed narrow-distributed star-shaped polyesters were successfully synthesized with high yields.

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页码：1491 / 1494

页数：4

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