Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase

被引：22

作者：

Vijaikanth, Vijendran

Capon, Jean-Francois

Gloaguen, Frederic

Petillon, Francois Y.

Schollhammer, Philippe

Talarmin, Jean

机构：

[1] CNRS, UMR 6521, UFR Sci & Tech, F-29238 Brest 3, France

[2] Univ Bretagne Occidentale, F-29238 Brest 3, France

[3] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 19期

关键词：

hydrogenase; di-iron complex; carboxy-functionalized dithiolate; molecular structure; Electrochemistry;

D O I：

10.1016/j.jorganchem.2007.06.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the di-iron complex [Fe-2(mu-S)(2)(CO)(6)](2-) with carboxy-functionalized dihalide derivatives (XCH2)(2)R (X = Cl, R = NC6H4CH2CO2CH3; X = Br, R = C6H3COOH, C6H3COON(COCH2)(2)) gave new functionalized dithiolate di-iron complexes [Fe-2(mu-SRS)(CO)(6)] (R = (CH2)(2)NC6H4CH2CO2CH3 (1), (CH2)(2)C6H3COOH (2), (CH2)(2)C6H3COON(COCH2)(2) (3)) in low yields. The azadithiolate complex 1 has been characterized by a single crystal X-ray diffraction analysis and studied by electrochemical methods. (c) 2007 Elsevier B.V. All rights reserved.

引用

收藏

页码：4177 / 4181

页数：5

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