Preparation and characteristic of triolein-embedded composite sorbents for water purification

被引:8
作者
Huo, JX [1 ]
Liu, HJ [1 ]
Qu, JH [1 ]
Wang, ZJ [1 ]
Ge, JT [1 ]
Liu, HN [1 ]
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Aquat Chem, Beijing 100085, Peoples R China
基金
中国国家自然科学基金;
关键词
triolein; cellulose acetate (CA); composite sorbent; persistent organic pollutants (POPs); dieldrin;
D O I
10.1016/j.seppur.2004.12.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The novel triolein-embedded composite sorbents for removing persistent organic pollutants (POPs) in water were developed. Comprehensive structural characteristics of the composite sorbents were characterized using scanning electron microscope (SEM), fourier transform infrared spectrum (FT-IR) and X-ray photoelectron spectrum (XPS). It is suggested that triolein/cellulose acetate (CA) viscous syrup can be deposited on the surface of silica gel granules, because the silica gel granules have the large enough aperture to make the polymer penetrate into. Triolein is also embedded into a hybrid membrane perfectly. Dieldrin is regarded as a representative compound of POPs. Sorption experiments in solutions with constant concentrations show that adsorption capacity increased with increased triolein content in composite adorbents. Dieldrin removal could reach 80% at 50 ng/l initial concentration, which is near the environmental level. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:37 / 43
页数:7
相关论文
共 27 条
[1]   Factorial design analysis for adsorption of dye on activated carbon beads incorporated with calcium alginate [J].
Annadurai, G ;
Juang, RS ;
Lee, DJ .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (02) :191-198
[2]   Photocatalytic water treatment: solar energy applications [J].
Bahnemann, D .
SOLAR ENERGY, 2004, 77 (05) :445-459
[3]   Polychlorinated biphenyls and hexachlorobenzene in atmosphere, sea-surface microlayer, and water measured with semi-permeable membrane devices (SPMDs) [J].
Booij, K ;
van Drooge, BL .
CHEMOSPHERE, 2001, 44 (02) :91-98
[4]  
BRIGGS D, 2001, SURFACE ANAL POLYM X, P70
[5]   PARTITION-COEFFICIENTS OF ORGANIC-COMPOUNDS IN LIPID WATER-SYSTEMS AND CORRELATIONS WITH FISH BIOCONCENTRATION FACTORS [J].
CHIOU, CT .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1985, 19 (01) :57-62
[6]   PARTITION-COEFFICIENT AND BIOACCUMULATION OF SELECTED ORGANIC CHEMICALS [J].
CHIOU, CT ;
FREED, VH ;
SCHMEDDING, DW ;
KOHNERT, RL .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1977, 11 (05) :475-478
[7]  
DONALD M, 1986, HDB LIPID RES, V4, P370
[8]   A comparison of organic contaminants in two high Arctic lake ecosystems, Bjornoya (Bear Island), Norway [J].
Evenset, A ;
Christensen, GN ;
Skotvold, T ;
Fjeld, E ;
Schlabach, M ;
Wartena, E ;
Gregor, D .
SCIENCE OF THE TOTAL ENVIRONMENT, 2004, 318 (1-3) :125-141
[9]   Adsorption kinetics of fluoride on low cost materials [J].
Fan, X ;
Parker, DJ ;
Smith, MD .
WATER RESEARCH, 2003, 37 (20) :4929-4937
[10]   Accumulation of organochlorine pesticides and PCBs by semipermeable membrane devices and Mytilus edulis in New Bedford Harbor [J].
Hofelt, CS ;
Shea, D .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (01) :154-159