Gold-catalyzed cyclization of enynes

被引：356

作者：

Ma, SM ^{[1
]}

Yu, SC ^{[1
]}

Gu, ZH ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 02期

关键词：

alcohols; cycloisomerization; enynes; gold; homogeneous catalysis;

D O I：

10.1002/anie.200502999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The key step in the gold-catalyzed cycloisomerization of enynes is the nucleophilic attack at the Au-coordinated C-C triple bonds to form a vinylic gold intermediate (see example). The homogeneous gold-catalyzed reaction of enynes under mild conditions has wide scope and high efficiency and gives access to complex or otherwise inaccessible products. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：200 / 203

页数：4

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