Stereocontrolled synthesis of either trans- or cis-trimethylsilylvinyloxiranes via sulfonium ylides

被引：26

作者：

Zhou, YG ^{[1
]}

Li, AH ^{[1
]}

Hou, XL ^{[1
]}

Dai, LX ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,SHANGHAI 200032,PEOPLES R CHINA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans- or cis-beta-Trimethylsilylvinyloxiranes are prepared by the reaction of aldehydes with a 3-trimethylsilylated dimethylsulfonium allylide under phase-transfer conditions or with a preformed 3-trimethylsilylated diphenylsulfonium allylide in the presence of LiBr, both in excellent yields and high stereoselectivity.

引用

页码：1353 / 1354

页数：2

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