Iridium-catalyzed H/D exchange

被引：36

作者：

Krüger, J ^{[1
]}

Manmontri, B ^{[1
]}

Fels, G ^{[1
]}

机构：

[1] Univ Gesamthsch Paderborn, Dept Chem, D-33098 Paderborn, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 2005卷 / 07期

关键词：

isotopic labelling; iridium; deuterium exchange;

D O I：

10.1002/ejoc.200400669

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The scope and limitation of an iridium-catalysed H/D exchange reaction has been investigated. Our results suggest a general mechanism for specific labelling at aromatic and non-aromatic double bonds by D2O if an electron-donating group is in a 1,4-relation with the carbon where the H/D exchange takes place. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：1402 / 1408

页数：7

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